منابع مشابه
9-Benzyl-3-bromo-9H-carbazole
The title compound, C(19)H(14)BrN, was synthesized by the N-alkyl-ation of (chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation = 0.013 Å) and forms a dihedral angle of 87.1 (2)° with the phenyl ring.
متن کامل9-Benzyl-9H-carbazole
The asymmetric unit of the title compound, C(19)H(15)N, contains two crystallographically independent mol-ecules. In both mol-ecules, the planar carbazole moieties [maximum deviations = 0.037 (4) and 0.042 (3) Å] are oriented with respect to the adjacent benzene rings, at dihedral angles of 85.29 (8) and 89.89 (7)°, respectively. In the crystal structure, weak C-H⋯π inter-actions are observed i...
متن کامل3-Bromo-9-(4-chlorobenzyl)-9H-carbazole
The title compound, C(19)H(13)BrClN, was synthesized by N-alkyl-ation of 4-chloro-1-(chloro-meth-yl)benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar, with a mean deviation of 0.028 Å, and it makes a dihedral angle of 91.2 (3) Å with the plane of the benzene ring.
متن کامل3-Bromo-9-(4-fluorobenzyl)-9H-carbazole
The title compound, C(19)H(13)BrFN, was synthesized by N-alkyl-ation of 1-chloro-methyl-4-fluoro-benzene with 3-bromo-9H-carbazole. The carbazole ring system is essentially planar (r.m.s. deviation of 0.024 Å for the non-H atoms) and forms a dihedral angle of 88.2 (3)° with the benzene ring.
متن کاملCrystal structure of 3-bromo-9-ethyl-9H-carbazole
In the title compound, C14H12BrN, the tricyclic ring system is essentially planar (r.m.s. deviation 0.026 Å). The carbon atoms of the ethyl group deviate from the mean plane by 0.148 (9) (CH2) and 1.59 (1) Å (CH3). In the crystal, H⋯π contacts [2.698-2.898 Å] shorter than the van der Waals contact distance of 3.70 Å are observed. A scalable to gram quantities selective synthesis of mono-bromine...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809024969